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11th Class Chemistry Guess Paper
11th Class Chemistry Important Short Questions
Question 2
- Determine the number of protons, neutrons, and electrons in an atom with Z = 17 and A = 35.
- Explain why the 4s subshell is filled before the 3d subshell in potassium.
- What information about an electron can be obtained from the Principal and Azimuthal quantum numbers?
- Define the Pauli Exclusion Principle and give an example.
- What does the (n + 1) rule represent in electronic configuration?
- Why are orbitals of the same subshell called degenerate?
- Differentiate between an orbit and an orbital.
- How many electrons can be accommodated in the M-shell? Explain using quantum numbers.
- Why does the f-subshell have 7 orbitals?
- Describe the significance of the magnetic quantum number.
- Explain why the atomic number is more fundamental than the mass number.
- Compare the mass of a neutron and a proton in amu.
- What happens to a neutron when passed through an electric field?
- Why is the deflection of electrons greater than that of protons in an electric field?
- Draw the orbital box diagram for phosphorus (Z = 15) adhering to Hund’s rule.
- Write the electronic configuration of Sodium (Na).
- Define the azimuthal quantum number (l).
- How many values of “l” are possible for n = 3?
- What is the maximum number of orbitals in the p-subshell?
- Distinguish between atomic emission and atomic absorption spectrum.
- What is 1st ionization energy? Give its standard unit.
- Explain why sulfur has a lower first ionization energy than phosphorus.
- The ionization energy of Be is higher than that of B. Justify this exception.
- Why does ionization energy decrease down a group?
- Explain why nitrogen has a higher ionization energy than oxygen.
- Define electronegativity and name the scale used to measure it.
- How does atomic size affect electronegativity?
- Why do noble gases have positive 1st electron affinities?
- Explain why the 2nd electron affinity of oxygen is positive (+844 kJ/mol).
- Why does fluorine have lower electron affinity than chlorine despite its smaller size?
- What is the shielding effect and how does it influence atomic radius?
- Define ionic radius and compare the size of Na and Na⁺.
- Why are anions always larger than their parent neutral atoms?
- Explain why Mg²⁺ is smaller than Na⁺.
- What happens to atomic radius across a period from left to right?
- Identify semi-metals in groups 14, 15, and 16.
- Illustrate how metallic character varies in group 14.
- Why do non-metals have higher electronegativity than metals?
- Explain the effect of nuclear charge on ionic size.
- Why is the 3rd ionization energy of magnesium much higher than its 2nd?
Period 3 Elements (Oxides & Chlorides) – Q.NO. 41–60
- Classify NaCl, MgCl₂, and PCl₅ as acidic, basic, or neutral.
- Why are the oxides of Na and Mg more ionic than the oxides of N and P?
- Describe the reaction of Na₂O with water and identify the product’s nature.
- Why is AlCl₃ considered an acidic halide while NaCl is neutral?
- Predict whether PCl₅ and NCl₅ would be acidic or basic.
- Why is SiO₂ considered an acidic oxide despite being a metalloid compound?
- Give the reaction of ZnO with both HCl and NaOH to prove its amphoteric nature.
- What causes the difference in oxidation numbers between SO₂ and SO₃?
- Why is sodium kept under kerosene oil while magnesium is not?
- Explain why magnesium reacts slowly with cold water but rapidly with steam.
- What is hydration in the context of neutral chlorides like NaCl?
- Compare the pH behavior of aqueous solutions of MgCl₂ and AlCl₃.
- Why do sulfur and phosphorus show variable oxidation numbers?
- Describe the nature of oxides formed by Period 3 non-metals.
- Write balanced equations for the reaction of Mg with oxygen.
- Explain the term “hydrolysis” in the context of acidic chlorides.
- Why is the oxidation number of 3rd-period elements in oxides always positive?
- Compare the reactivity of Na and Mg toward chlorine.
- What is the important function of the “stair-step line” on the periodic table?
- How does electronic configuration help determine the block of an element?
Reaction Kinetics – Q.NO. 61–90
- Define the rate of a reaction and give its units.
- Differentiate between average rate and instantaneous rate.
- Why does the instantaneous rate of a reaction decrease with time?
- Define “Activation Energy” and its role in a chemical reaction.
- Explain why wood burns more rapidly in pure oxygen than in air.
- How does temperature affect the collision frequency of molecules?
- What is the Boltzmann distribution curve?
- Explain why a 10°C rise in temperature approximately doubles the reaction rate.
- Define a catalyst and explain how it affects activation energy.
- Differentiate between homogeneous and heterogeneous catalysis.
- What is the “Order of Reaction”? How is it experimentally determined?
- Define the specific rate constant (k).
- Why is the sum of coefficients in a balanced equation not always equal to the order?
- Give an example of a zero-order reaction.
- Define molecularity and distinguish it from the order of reaction.
- What is the role of proper molecular orientation in collision theory?
- How does the surface area of a solid reactant affect the rate of reaction?
- Why is the rate of reaction highest at the beginning?
- Give an example of a biological catalyst (enzyme).
- What is a photochemical reaction? How does light affect its rate?
- Calculate the overall order for: rate = k[NO]²[NH₃]⁰.
- Why do chemists need to know the rate constant for a reaction?
- How does the nature of reactants (ionic vs. covalent) affect the rate?
- Describe the effect of a catalyst on the “alternative path” of a reaction.
- What is meant by “effective collisions”?
- State the units of the rate constant for a first-order reaction.
- How can color change be used to monitor the progress of a reaction?
- Define “Fast Reactions” with an example.
- Why is pressure important for the rate of gaseous reactions?
- Explain why a catalyst is not consumed in a reaction.
Chemical Equilibrium – Q.NO. 91–120
- Define a reversible reaction with a suitable example.
- What are the macroscopic characteristics of chemical equilibrium?
- Why does a reversible reaction never go to completion?
- Explain the term “Dynamic Equilibrium.”
- Define the Equilibrium Constant (Kc).
- Write the expression for N₂(g) + 3H₂(g) ⇌ 2NH₃(g).
- Why does a catalyst have no effect on the value of Kc?
- State Le-Chatelier’s Principle.
- Explain the effect of increasing the concentration of reactants on equilibrium.
- How does a change in pressure affect equilibrium if the number of moles of gas is equal on both sides?
- Why is temperature the only factor that changes the value of Kc?
- In an exothermic reaction, in which direction does the equilibrium shift if heat is added?
- Describe the effect of pressure on the synthesis of Ammonia (Haber’s Process).
- Why are pure solids and liquids excluded from the Kc expression?
- Explain the soda water bottle equilibrium: CO₂(g) + H₂O(l) ⇌ HCO₃⁻(aq) + H⁺(aq).
- What happens to the equilibrium in a soda bottle when the cap is removed?
- Differentiate between homogeneous and heterogeneous equilibria.
- What does a very large value of Kc indicate about the extent of a reaction?
- How is the equilibrium constant related to the rates of forward and backward reactions?
- Explain why a closed system is necessary for establishing equilibrium.
- If Qc < Kc, what does it tell you about the concentrations of reactants and products?
- Define the “Position of Equilibrium.”
- How does the removal of a product affect the yield in a reversible reaction?
- Explain the effect of decreasing volume on the reaction: PCl₅(g) ⇌ PCl₃(g) + Cl₂(g).
- Why does equilibrium shift to the left in an exothermic reaction when heated?
- Discuss the industrial importance of Le-Chatelier’s Principle.
- What is the response of an endothermic reaction to a decrease in temperature?
- In the reaction BiCl₃ + H₂O ⇌ BiOCl + 2HCl, what happens when HCl is added?
- Does a catalyst change the position of equilibrium? Explain.
- Explain why Kc has no units in some reactions.
Halogens – Q.NO. 121–150
- Why are halogens called “salt formers”?
- Explain the trend of volatility in halogens from fluorine to iodine.
- Why is fluorine the most powerful oxidizing agent?
- Describe the role of London dispersion forces in the physical states of halogens.
- Why is the F-F bond weaker than the Cl-Cl bond?
- Explain why HF is a weaker acid than HCl in aqueous solution.
- What is a disproportionation reaction? Give the reaction of chlorine with water.
- Why does the reactivity of halogens with hydrogen decrease down the group?
- Name the halogen used as an antiseptic and explain how it works.
- Describe a chemical test to distinguish between Bromide and Iodide ions.
- Why is HOCl a more effective disinfectant than OCl⁻?
- Write the ionic equation for the displacement of Iodine by Bromine.
- Which halogen is the most volatile? Explain based on intermolecular forces.
- What are the primary active species in the chlorination of water?
- Why is chlorine used in the purification of drinking water?
- Explain the color change when chlorine gas is passed through a KI solution.
- How does the electronegativity of halogens vary down the group?
- Why can’t iodine displace bromine from its salt?
- Write the oxidation state of Chlorine in HClO and HClO₃.
- What is the physical state of Iodine at room temperature? Why?
- Explain how bond length affects bond strength in halogens.
- What are hydrogen halides? Name the most stable one.
- Write the conditions required for the reaction of Iodine with Hydrogen.
- Why is fluorine gas extremely reactive even in the dark?
- Compare the oxidizing power of Cl₂ and Br₂.
- How is HCl formed in the lab? Write the reaction.
- What is the environmental concern regarding the chlorination of water?
- Explain the ionization of halogen acids in water.
- Why does iodine have a higher melting point than other halogens?
- Describe the reactivity of halogens with cold and hot NaOH.
Periodic Trends – Q.NO. 151–170
- Why do some elements show variable oxidation numbers?
- Define the Modern Periodic Law.
- What does the period number of an element indicate about its shells?
- Explain why lithium, sodium, and potassium have similar chemical properties.
- Why are noble gases placed at the end of each period?
- How can ionization energy data predict the number of valence electrons?
- Differentiate between paired and unpaired electrons.
- What is the significance of arrow direction in orbital diagrams?
- Why does electron pairing occur only after a subshell is half-filled?
- Explain the role of surface area in solid-gas reactions.
- What is an enzyme? Give an example of its catalytic action.
- How does pressure affect the synthesis of SO₃ in the Contact Process?
- Define “Macroscopic Events” in a chemical reaction.
- Why is a large jump seen in the successive ionization energies of magnesium?
- What is the relationship between group number and valence electrons?
- Explain the term “Effective Nuclear Charge” (Zeff).
- Why do atoms become smaller from left to right in a period?
- Define the “Spin-Pair Repulsion” effect.
- Why is the second electron affinity of oxygen positive?
- How does the shielding effect influence the electronegativity of elements in a group?
Reactivity of Elements – Q.NO. 171–180
- Why are elements on the left side of the periodic table considered metals?
- Compare the reactivity of Na and Mg with oxygen.
- Why does sodium form both an oxide and a peroxide?
- Write the formula of the chloride of a group 15 element.
- Differentiate between acidic and basic oxides with reactions.
- Explain why AlCl₃ is acidic while NaCl is neutral.
- How is the oxidation number of a third-period element generally related to its group?
- Why is the atomic number more fundamental than the mass number?
- Find the number of neutrons in ³¹P₁₅.
- Explain why the Cl⁻ ion has more electrons than protons.
Atomic Structure Review – Q.NO. 181–190
- Define the term “Orbit.”
- How do the values of “l” determine the type of subshell (s, p, d, f)?
- Why are px, py, and pz orbitals called degenerate?
- State Hund’s Rule of maximum multiplicity.
- Explain the importance of the rate law in chemistry.
- Why is molecularity always a whole number?
- How does the removal of a product affect the direction of a reversible reaction?
- What is the response of an equilibrium system to a decrease in temperature in an exothermic reaction?
- Why is Kc constant at a given temperature?
- Describe the effect of volume increase on the reaction: N₂(g) + 3H₂(g) ⇌ 2NH₃(g).
Miscellaneous Short Questions – Q.NO. 191–200
- Why does a catalyst speed up both forward and reverse reactions equally?
- Compare the bond strengths of Cl-Cl and Br-Br.
- What is observed when chlorine reacts with KI solution?
- Explain why HF is more stable than other hydrogen halides.
- How does HClO act on microorganisms to kill them?
- Write the electronic configuration of an element in Period 4, Group 2.
- Why does metallic character increase down a group?
- Explain why nitrogen has a higher ionization energy than oxygen.
- What is the significance of the “rate-determining step” in a reaction?
- Define “Amphoteric Oxides” with the example of Aluminum Oxide (Al₂O₃).
Question 3
VSEPR & Hybridization – Q.NO. 1–20
- By counting electron pairs around the central atom, explain why xenon trioxide (XeO₃) has a pyramidal shape.
- Explain the difference between the formation of σ and π bonds.
- Show how the central carbon atom in propanone forms σ and π bonds through hybridization.
- Predict the shapes of sulfate (SO₄²⁻), borate (BH₄⁻), and tri-iodide (I₃⁻) ions according to VSEPR.
- Sketch the hybrid orbitals and bond formation in PCl₃, SiCl₄, and NH₄⁺.
- Draw the orbital structures of the CO₂ molecule in terms of Valence Bond Theory (VBT).
- Can you explain why CO has a dipole moment but CO₂ does not?
- Do you think that individual bonds in CCl₄ are polar? Explain in terms of electronegativity.
- Draw the Lewis structures for IF₃ and IF₅ and predict their geometry.
- HI is a strong acid and a robust reducing agent, whereas HF is a weaker acid. Explain.
- Differentiate between s-s overlap and s-p overlap.
- Why are covalent bonds directional in nature?
- Explain the bonding in Cl₂ molecule using orbital overlap.
- How does the π bond form in O₂?
- Why does H₂S have a bent shape instead of linear?
- Define sp³ hybridization and give the example of methane (CH₄).
- Differentiate between sp and sp³ hybridization in terms of bond angle and geometry.
- Why is the energy of hybrid orbitals lower than that of unhybridized orbitals?
- What type of hybridization is present in BeCl₂?
- Why does BF₃ have a trigonal planar shape?
Thermochemistry – Q.NO. 21–40
- Define Bond Order.
- Explain why the enthalpy of hydration is always an exothermic process for gaseous ions.
- Define standard enthalpy of atomization with an example.
- The enthalpy of solution can be positive or negative. Explain what this indicates.
- Calculate ΔH° for the formation of methane using enthalpies of combustion of C, H₂, and CH₄.
- State Hess’s Law and explain its advantage.
- Define Bond Dissociation Energy.
- Why is bond energy always positive?
- Define Specific Heat Capacity. What is its value for water?
- Explain the meaning of each symbol in the formula q = mcΔT.
- Define Lattice Energy.
- Define Hydration Energy.
- Why is lattice breaking endothermic while hydration is exothermic?
- What is a Born-Haber cycle?
- Is electron affinity exothermic or endothermic? Explain.
- Standard enthalpy of combustion of ethanol?
- Why are bond energies different in different compounds for the same bond?
- What happens to energy when a chemical bond is formed?
- Explain the Joule-Thomson effect.
- Why can gases be compressed easily?
Intermolecular Forces & States of Matter – Q.NO. 41–70
- Which forces are present among the molecules of CCl₄ and SiF₄?
- Differentiate between instantaneous dipole-induced dipole (id-id) and permanent dipole (pd-pd) forces.
- Can the CHF₃ molecule make a hydrogen bond? Explain.
- Show a hydrogen bond between two molecules of ethanol.
- Explain why the boiling point difference decreases as the size of the alcohol molecules increases.
- Why is the viscosity of honey higher than water?
- Which is more viscous: glycerine or hexane? Why?
- Why does evaporation get faster at higher temperatures?
- Why is food cooking difficult in areas with high altitudes?
- Explain why food cooks faster in a pressure cooker.
- Why is the boiling point of water (100°C) higher than that of ethanol (78°C)?
- What is meant by the “habit of a crystal”?
- Name the properties of liquid crystals in which they resemble solids.
- Which property of liquid crystals makes them useful in temperature sensing devices?
- Why do solids not undergo translatory motion?
- Why does iodine exist as a solid at room temperature?
- Why does HF have a higher boiling point than HCl?
- Why do boiling points of halogens increase down the group?
- Why is HF less acidic than HCl despite stronger bonding?
- Define Surface Tension and Viscosity.
- Why can insects like mosquitoes walk on the surface of water?
- What happens to the surface tension of water when temperature increases?
- Why does vapour pressure increase with temperature?
- Explain why vapour pressure is independent of container size.
- Why are liquid crystals always anisotropic?
- How are liquid crystals used in breast cancer diagnosis?
- Define Crystal Lattice and Unit Cell.
- Why do crystalline solids have sharp melting points?
- Explain how urea impurity affects the habit of an NaCl crystal.
- Why is water more effective in temperature regulation than other liquids?
Thermochemistry (Continued) – Q.NO. 71–90
- Differentiate between exothermic and endothermic reactions with examples.
- What do you understand by the enthalpy of a system?
- Distinguish clearly between standard enthalpy of reaction and standard enthalpy of formation.
- Define and give one example of: Standard enthalpy of solution and hydration.
- Explain why the lattice enthalpy of an ionic compound is typically a large negative value.
- Explain why the enthalpy of hydration is always an exothermic process for gaseous ions.
- Define standard enthalpy of atomization with an example.
- The enthalpy of solution can be positive or negative. Explain what this indicates.
- Draw energy profile diagrams for the combustion of methane and decomposition of calcium carbonate.
- Calculate ΔH° for the formation of methane using enthalpies of combustion of C, H₂, and CH₄.
- State Hess’s Law and explain its advantage.
- Calculate the enthalpy change for the Haber process using bond energies (N≡N, H-H, N-H).
- Define Bond Dissociation Energy.
- Why is bond energy always positive?
- Define Specific Heat Capacity. What is its value for water?
- Explain the meaning of each symbol in the formula q = mcΔT.
- Why is insulation used in a calorimeter?
- Define the calorie content of food in terms of energetics.
- Give the combustion equation of glucose with its ΔH value.
- On which fundamental law is Hess’s Law based?
Born-Haber Cycle & Bond Energies – Q.NO. 91–100
- Why is Hess’s Law important for reactions that are too slow or have side reactions?
- Define Lattice Energy.
- Define Hydration Energy.
- Why is lattice breaking endothermic while hydration is exothermic?
- What is a Born-Haber cycle?
- Name the steps involved in the Born-Haber cycle of NaCl.
- Is electron affinity exothermic or endothermic? Explain.
- What is the standard enthalpy of combustion of ethanol?
- Why are bond energies different in different compounds for the same bond?
- What happens to energy when a chemical bond is formed?
Organic Chemistry – Q.NO. 1–25
- Differentiate between Aliphatic and Aromatic hydrocarbons.
- Differentiate between Homolytic and Heterolytic Fission.
- Define Electrophile and Nucleophile with examples.
- Explain why alkanes do not undergo addition reactions.
- Explain why 2-bromopropane is the major product when propene reacts with HBr.
- Explain how inductive effects from alkyl groups stabilize carbocations.
- Write down structural formulas for 2-methylbutane and 2,2-dimethylpropane.
- Give two differences between molecules of cyclopentane and pentane.
- Why do branched alkanes have lower boiling points than straight-chain alkanes?
- Explain why alkanes have a tetrahedral shape.
- Explain why alkanes are highly stable (paraffins).
- Explain the mechanism of halogenation of methane.
- Give the dehydrohalogenation reaction of bromopropane.
- How does an alkane differ from an alkene in terms of stability?
- Why is the order of stability of carbocations 3° > 2° > 1°?
- Compare the relative rates of addition to alkenes for HCl, HBr, and HI.
- Explain how Markovnikov’s rule is applied in the addition of HBr to 2-pentene.
- What is a free radical?
- Why are alkenes called olefins?
- Describe geometrical isomerism (cis-trans) in alkenes.
- How can you distinguish between an alkane and an alkene using bromine water?
- Which bond is weaker in a double bond: sigma or pi?
- State the bond angle in ethene (120°).
- Why is the boiling point of CH₃OH (65°C) much higher than CH₃CH₃ (-89°C)?
- Why does CCl₄ have higher viscosity than CHCl₃ but less than ethanol?
Miscellaneous Short Questions (States of Matter & Hess’s Law) – Q.NO. 26–30
- Why does evaporation continue even at room temperature?
- Why do we feel cool near the bank of a river?
- What does the peak in an energy profile diagram represent?
- What happens to the energy of a system when a bond is broken?
- What is meant by “indirect route” in Hess’s Law?
Periodic Trends Review – Q.NO. 31–50
- Define Modern Periodic Law.
- Why does atomic radius decrease across a period?
- Why does atomic radius increase down a group?
- Define Ionization Energy and give its trend in the periodic table.
- Why does shielding effect reduce ionization energy?
- Explain why the second ionization energy of Calcium is higher than the first.
- Why do noble gases have the highest ionization energies?
- Why is the first electron affinity of Oxygen negative while the second is positive?
- Differentiate between Electron Affinity and Electronegativity.
- Explain the trend of Electronegativity across a period.
- Why is the ionic radius of a cation smaller than its parent atom?
- Why is the ionic radius of an anion larger than its parent atom?
- Compare the reactivity of Sodium and Magnesium with water.
- Classify Na₂O, Al₂O₃, and SO₂ as acidic, basic, or amphoteric.
- Why does AlCl₃ behave as an acidic chloride in water?
- What happens when sodium burns in excess oxygen?
- Explain the variation of metallic character in the periodic table.
- Define Amphoteric Oxides with a chemical equation.
- What is the oxidation state of Phosphorus in PCl₃ and PCl₅?
- Why do chlorides of Group 1 and 2 elements form neutral solutions?
Atomic Structure (Detailed) – Q.NO. 51–70
- Define Atomic Number and Nucleon Number.
- Describe the behavior of protons, neutrons, and electrons in an electric field.
- What are isotopes? Give the neutron count for Cl-35 and Cl-37.
- Explain the Principal Quantum Number (n).
- What does the Azimuthal Quantum Number (l) determine?
- Describe the Magnetic Quantum Number (m).
- State the Pauli Exclusion Principle.
- State Hund’s Rule of Maximum Multiplicity.
- Explain the Aufbau Principle.
- Sketch the shape of a p-orbital.
- Why is the electronic configuration of Chromium (Cr) anomalous?
- Why is the electronic configuration of Copper (Cu) anomalous?
- What is a free radical? Give an example.
- How are n-type semiconductors formed?
- How are p-type semiconductors formed?
- Define Exothermic and Endothermic reactions with sign of ΔH.
- State Hess’s Law of Constant Heat Summation.
- Define Standard Enthalpy of Formation (ΔHf°).
- Define Standard Enthalpy of Combustion (ΔHc°).
- Define Enthalpy of Atomization (ΔHat°).
Thermochemistry & States of Matter – Q.NO. 71–100
- Define Standard Enthalpy of Neutralization.
- Define Lattice Energy.
- What is the Born-Haber Cycle?
- Why is bond breaking an endothermic process?
- Why is heat of neutralization of strong acid and strong base constant?
- Define Hydrogen Bonding.
- Why does ice have a lower density than liquid water?
- What are Liquid Crystals?
- Define London Dispersion Forces.
- Why does evaporation cause cooling?
- State the Law of Mass Action.
- Define Chemical Equilibrium.
- Write the Equilibrium Constant (Kc) expression for aA + bB ⇌ cC + dD.
- Differentiate between Homogeneous and Heterogeneous Equilibrium.
- What is the relationship between Kp and Kc?
- How does temperature affect the equilibrium constant (Kc)?
- Why is chemical equilibrium dynamic?
- What is Le Chatelier’s Principle?
- Effect of pressure on the synthesis of Ammonia (N₂ + 3H₂ ⇌ 2NH₃).
- Does a catalyst affect the equilibrium constant?
- What are “families” in the periodic table? Name two.
- Explain the term “Blocks” in the periodic table.
- What is the role of liquid crystals in medicine?
- Why are solids incompressible?
- Define Unit Cell.
- What is hydration energy?
- Why is the second electron affinity of Oxygen endothermic?
- What is the shape of an ethene molecule?
- Define Isomerism.
- What is the general formula of Alkanes and Alkenes?
Question 4
Mole Concept & Stoichiometry – Q.NO. 1–20
- How is the concept of mole derived from Avogadro’s number (NA)?
- Define: (a) Molar mass (b) Molar volume (c) Molar concentration.
- 39 g of Potassium (K) and 56 g of Iron (Fe) have equal number of atoms in them. Justify.
- 4 g of Helium (He), 17 g of Ammonia (NH₃), and 64 g of Sulfur Dioxide (SO₂) occupy 22.414 dm³ at STP despite different sizes. Explain.
- Differentiate theoretical and actual yields.
- What are the factors mostly responsible for the low yield of products in chemical reactions?
- Calculate the molar mass of Potassium Permanganate (KMnO₄).
- How many molecules are present in 1.75 g of Hydrogen Peroxide (H₂O₂)?
- How many atoms are present in a 15 g Gold (Au) ring?
- Determine the volume of 2.5 moles of Chlorine molecules (Cl₂) at STP.
- Calculate the molar mass of a gas which has a density of 1.97 g/dm³ at STP.
- Calculate the molar concentration of a solution containing 7.9 g of KMnO₄ dissolved in 1 dm³ (Molar mass = 158).
- When 3.3 moles of Nitrogen react with Hydrogen, how many moles of Hydrogen are consumed to form Ammonia?
- Define Stoichiometry. Mention its two basic assumptions.
- Calculate the mass of Aluminum (Al) needed to react with 32.0 g of Iron(III) Oxide (Fe₂O₃) to produce Iron.
- What is the mass of 10⁻³ mol of Magnesium Sulfate (MgSO₄)?
- How many molecules are in 1 × 10⁻⁶ g of isopentyl acetate (C₇H₁₄O₂)?
- Calculate the volume of CO₂ produced at STP when 4.5 dm³ of Methane (CH₄) is burnt.
- Why does 1 mole of Uranium weigh more than 1 mole of Hydrogen?
- Define oxidation and reduction in terms of electron transfer with examples.
Redox Reactions & Electrochemistry – Q.NO. 21–50
- Define oxidation and reduction in terms of change in oxidation number.
- Determine the Oxidation Number of: (i) Cr in K₂Cr₂O₇ (ii) N in NO₃⁻.
- Identify the oxidized and reduced species in: Fe₂O₃ + 3CO → 2Fe + 3CO₂.
- Define a Disproportionation reaction with an example involving Chlorine.
- Balance the equation: MnO₂ + HCl → MnCl₂ + Cl₂ + H₂O.
- Balance the equation: K₂Cr₂O₇ + FeSO₄ + H₂SO₄ → Cr₂(SO₄)₃ + Fe₂(SO₄)₃ + K₂SO₄ + H₂O.
- Explain the construction and function of a Salt Bridge in a galvanic cell.
- During electrolysis of aqueous NaCl, why is H₂ liberated at the cathode?
- Define Standard Hydrogen Electrode (SHE). What is its potential?
- How and why is an electrical double layer formed?
- Why is the electrode potential of Cu called reduction potential?
- Calculate the standard cell potential (E°cell) for a Ni-Co cell.
- What is the effect of variation in ion concentration on the standard electrode potential?
- Arrange Ag, Cr, and Fe in increasing order of their reducing powers based on E° values.
- Describe the redox changes during the electrolysis of molten CuBr₂.
- What happens if the salt bridge is removed from a galvanic cell?
- Why is DC used instead of AC in electrolysis?
- Define Electrolysis. How is it used to refine metals?
- Calculate the voltage of a cell having iron and copper electrodes (E°Fe = -0.44V, E°Cu = +0.34V).
- Explain why the electrode potential is measured relatively using SHE.
- Describe the movement of ions through the salt bridge.
- (Skipped in numbering)
- Calculate the mass of 1.5 moles of Ca(OH)₂.
- Determine the number of molecules in 1.75 g of water.
- How many atoms of Carbon are in 1 mole of isopentyl acetate?
- Define Molar Volume. What is its value at STP?
- State Avogadro’s Law in terms of gas volumes.
- Calculate the mass of sodium hypochlorite produced from 2.25 moles of chlorine.
- Balance: MnO₂ + HCl → MnCl₂ + Cl₂ + H₂O.
- Calculate the Ox. No. of Chromium in Cr₂O₇²⁻.
Nitrogen & Its Compounds – Q.NO. 51–66
- List two reasons for the chemical inertness of N₂ gas.
- Why is ammonia (NH₃) considered a weak base?
- Describe the laboratory preparation of ammonia gas.
- Why is N₂ gas used in food packaging?
- Both CO and N₂ have triple bonds. Why is CO more reactive?
- Why shouldn’t a farmer treat a field with ammonium fertilizer and lime at the same time?
- Draw the structures of N₂O, NO, and NO₂ and explain their bonding.
- Explain why sulfur is unreactive at room temperature.
- Determine the oxidation state of S in: H₂SO₄ and S₂O₃²⁻.
- Explain the involvement of d-orbitals in the variable oxidation states of sulfur.
- What is the role of sulfur in the vulcanization of rubber?
- Give the reaction of Sulfur with NaOH.
- What is the function of SO₂ and sulfite salts in food preservation?
- Explain the oxidation of SO₂ to SO₃.
- Why does sulfur show more oxidation states than oxygen?
- Compare the reactions of sulfur with metals and non-metals.
Environmental Chemistry – Q.NO. 67–100
- What does PAN stand for? Give its general formula.
- Describe the role of a catalyst in a catalytic converter.
- Write the conversion reaction carried out by Nitrobacter.
- Explain why denitrification occurs in anaerobic conditions.
- Name the four major layers of the atmosphere and their approximate heights.
- Why is the Troposphere the most important layer for life?
- Explain why the Stratosphere is warmer than the Mesosphere.
- Give the equations for the formation and depletion of ozone in the stratosphere.
- Identify three major natural sources of air pollutants.
- Differentiate between Classical and Photochemical smog.
- Name the major Greenhouse Gases (GHGs). How do they cause global warming?
- What are the main chemical processes involved in the formation of Acid Rain?
- How do volatile organic compounds (VOCs) affect air quality?
- What is the impact of PAN on human health and plants?
- How does deforestation impact air quality and CO₂ levels?
- Why is CO called a “silent killer”?
- Explain the principle of Winkler’s method to determine Dissolved Oxygen (DO).
- Define BOD. How is it carried out?
- Why are BOD and DO inversely related in polluted water?
- What are the anthropogenic sources of NOx?
- Explain how NO₂ contributes to the brown color of smog.
- What is the role of sunlight in photochemical smog formation?
- How do particulates (Particulate Matter) cause lung damage?
- Write a balanced equation for the formation of sulfuric acid from atmospheric SO₃.
- Explain the “Greenhouse Effect” in terms of heat absorption.
- What are the effects of SO₂ on plants and aquatic life?
- What is the common name of N₂O?
- Which nitrogen oxide is paramagnetic?
- Which nitrogen oxide is used in rocket propellants?
- List two natural sources of NOx.
- Define Anthropogenic sources of pollution.
- What gives the brown color to urban smog?
- Explain the role of sunlight in smog formation.
- Name the metals used in a catalytic converter.
Nitrification & Sulfur – Q.NO. 101–116
- Define Nitrification and name the bacteria involved.
- Write the conversion reaction of NH₄⁺ to NO₂⁻.
- What is the atomic number and physical state of sulfur?
- Define Catenation in sulfur.
- Which is the most stable molecular form of sulfur?
- Compare oxidation states of sulfur in SO₂ and H₂SO₄.
- Explain the stability of the +6 oxidation state in SO₃.
- What happens when SO₂ is dissolved in water?
- Why is SCl₂ unstable in moist air?
- How is sulfur used in the bleaching of paper?
- Describe the role of sulfur in making dyes and explosives.
- How is sulfuric acid used in the battery industry?
- What is the physical appearance of sulfur?
- Explain the role of sulfur in the vulcanization of rubber.
- Which atmospheric layer contains the ozone layer?
- Why is the Mesosphere the coldest layer?
Ozone & Air Pollution – Q.NO. 117–144
- Describe how UV radiation contributes to ozone formation.
- Name two primary air pollutants.
- Give an example of a secondary pollutant.
- How are secondary pollutants formed?
- Why are aerosols harmful?
- Why is fossil fuel combustion a major cause of air pollution?
- How does agriculture release ammonia into the air?
- Compare industrial and domestic sources of air pollutants.
- What is the impact of urbanization on air quality?
- What is global warming?
- Which gas has the highest heat-absorbing potential?
- How do particulates cause cardiovascular issues?
- What is the impact of PAN on plant life?
- Explain the role of NO₂ in acid rain.
- How can smog formation be reduced in cities?
- Define the Greenhouse Effect.
- Name one heavy metal pollutant affecting human health.
- Why are motor vehicles considered mobile pollution sources?
- Calculate moles of HCl neutralized by 2.1 g of baking soda (NaHCO₃).
- What volume of H₂ at STP is produced from 7.0 g of Iron and H₂SO₄?
- Differentiate between Actual Yield and Percentage Yield.
- Why must electrons lost equal electrons gained in balancing redox reactions?
- Define Oxidation Number.
- Find the Oxidation Number of Mn in KMnO₄.
- Why is the mole used by chemists as a unit?
- How is molar mass related to the periodic table?
- Do 1 mole of glucose and 1 mole of water contain equal molecules?
- What happens to a cation during electrolysis?
Click Here for 1st Year Chemistry MCQs
11th Class Chemistry Important Long Questions
Question NO. 5
- Explain the four quantum numbers with their names, symbols, possible values, and significance. Also write their formulae where applicable.
- Draw the shapes of s, p, and d-orbitals. Justify these by keeping in view the azimuthal and magnetic quantum numbers.
- Describe Aufbau Principle, Pauli Exclusion Principle, and Hund’s Rule with diagrams.
- Discuss the variation of first ionization energies across a period and down a group with reasons.
- Explain the Bohr and Schrodinger models of the atom. How did the concept of energy levels change with quantum mechanics?
- Explain the method to determine the number of protons, neutrons, and electrons in atoms and ions, with the help of suitable examples.
- Hydrogen bonding is present in H₂O, NH₃, HF, (CH₃)₂CO and CHCl₃ molecules. Sketch structures and discuss briefly.
- Compare the hydrogen bonding in water, ammonia, and hydrogen fluoride. How does this bonding affect their physical states and boiling points?
- What are London dispersion forces? Give examples, and discuss the factors affecting these forces.
- Discuss the structural changes when water turns into ice. Justify the empty spaces in its crystals as compared to H₂O at 4°C and lower density of ice.
- Discuss the factors that affect the boiling point of liquids with examples. Explain how intermolecular forces influence the boiling points of water and ethanol.
- What are liquid crystals? How are they different from solids and liquids? Explain with their properties and uses.
- Compare crystalline and amorphous solids.
- Describe the following properties of crystalline solids: (i) Geometrical shape (ii) Melting point (iii) Cleavage plane (iv) Habit of a crystal.
- Explain the Ideal Gas Equation (PV = nRT).
Question NO. 6
- What are the postulates of VSEPR model? Discuss the structures of the following species with reference to this theory: (i) CH₄ (ii) NH₃ (iii) H₂O⁺ (iv) PCl₃ (v) SO₂ (vi) SF₆.
- Explain the orbital hybridization for CH₄, NH₃, BF₃ and BeCl₂.
- Describe the molecular orbital diagram of oxygen (O₂). Explain its bond order and magnetic behavior.
- Draw and explain the molecular orbital diagram for nitrogen (N₂). What type of bonding exists?
- Differentiate between Sigma and Pi Bonds in detail.
- Differentiate between sp, sp², and sp³ hybridization.
- Explain the postulates of collision theory. Also describe the terms “effective collision” and “activation energy” with the help of diagrams or examples.
- Explain how a catalyst works. Support your answer with an energy profile diagram.
- Discuss in detail the five major factors that affect the rate of a chemical reaction with examples.
- Explain the difference between order of reaction and molecularity with examples.
- Define rate law, rate constant, and order of reaction. Derive units of k for first and second-order reactions.
- Relate the order of a reaction to the rate law for the reaction. How do you distinguish between zero order, first order and second order reaction?
- Calculate the reaction rate if the concentration of A is 0.5 M, the concentration of B is 0.2 and the rate constant k is 4.0 M⁻¹. Given the rate law for a reaction: Rate = k[A][B]².
Question NO. 7
- Define and explain the law of mass action and derive the expression for the equilibrium constant (Kc) for a general reaction: aA + bB ⇌ cC + dD.
- State Le-Chatelier’s Principle. Explain its application with respect to changes in concentration, temperature, pressure, and use of a catalyst.
- Synthesis of ammonia by Haber’s process is an exothermic reaction. What should be the possible effect of change of temperature, pressure, and concentration at the equilibrium stage?
- The change of volume or pressure for the following reactions only changes the equilibrium position. Discuss how the direction changes for: (i) 2H₂ + O₂ ⇌ 2H₂O (ii) N₂O₄ ⇌ 2NO₂.
- Ethanol reacts with ethanoic acid to form ethyl ethanoate and water.
- Propanoic reacts with hydrogen cyanide. At equilibrium, the concentration of the product is 0.0233 mol dm⁻³. Calculate Kc given initial concentrations were 0.0500 mol dm⁻³.
- Define pH and pOH. Derive their mathematical expressions and prove that pH + pOH = 14 at 25°C.
- Define ionization constant (Ka) of acids. Derive the expression for Ka of a weak acid and explain its significance in distinguishing strong vs. weak acids.
- What is a buffer solution? Explain the working mechanism of acidic (CH₃COOH/CH₃COONa) and basic buffers with examples.
- What is the common ion effect? Explain with examples how the addition of a common ion affects the ionization of weak acids using Le Chatelier’s Principle.
- The ionic product of water (Kw) is 1.0 × 10⁻¹⁴ at 25°C. If [H⁺] = 1.0 × 10⁻⁷ M, calculate [OH⁻], pH, and pOH.
- Explain the use of Solubility Product (Ksp) in predicting precipitation vs. solubility.
- Calculate the solubility of a sparingly soluble salt lead (II) iodide (PbI₂) in water. It has Ksp = 1.4 × 10⁻⁸.
- Ca(OH)₂ is a sparingly soluble compound. Its solubility product is 6.5 × 10⁻⁶. Calculate the solubility of Ca(OH)₂.
- A buffer solution has a pH of 5.0. It is made from a weak acid HA with a pKa of 4.8. What is the ratio of [A⁻] to [HA]?
Question NO. 8
- Describe the halogenation of methane using the free radical chain mechanism. Include initiation, propagation, and termination steps.
- Describe the mechanism of electrophilic addition of hydrogen halides to alkenes. Discuss Markovnikov’s Rule in the context of hydrogen halide addition.
- Describe the important reactions of alkenes including hydrogenation, halogenation, hydration, and ozonolysis with equations.
- Describe the following methods for the preparation of alkenes: (i) Dehydrohalogenation of alkyl halides (ii) Dehydration of alcohols.
- Explain the structure and bonding in ethene. How does it affect the reactivity of alkenes?
- What is geometrical isomerism in alkenes? Illustrate your answer with appropriate structural examples.
- Explain the characteristics, height ranges, and temperature variations of the four main layers of the atmosphere.
- Write short notes on the following: (i) CFCs and ozone layer depletion (ii) Greenhouse effect and global warming.
- How does fossil fuel burning cause acid rain? Discuss in detail with chemical reactions.
- Discuss the effects of major air pollutants (CO, SO₂, NO, O₃, PAN, particulates) on human health and the environment.
- Define primary and secondary pollutants. Explain their sources and harmful effects with examples.
- Explain the major natural and anthropogenic (man-made) sources of air pollution with examples.
Question NO. 9
- Describe the industrial and laboratory preparation of ammonia. Also give chemical equations and tests for its identification.
- How oxides of nitrogen (NOx) cause the formation of photochemical smog and PAN? Give its mechanism.
- Describe the processes of nitrification and denitrification with the help of relevant chemical equations and bacterial names.
- Explain the Bronsted-Lowry basic character of ammonia. How is it converted into NH₄⁺ ion and what is the geometry of this ion?
- Discuss the structures, oxidation states, physical properties, and uses of at least three oxides of nitrogen.
- Describe the different oxidation states shown by sulfur and explain their stability with reference to compounds like H₂S, SO₂, SO₃, and S₈.
- Discuss the important chemical reactions of sulfur with oxygen, hydrogen, chlorine, water, and metals. Include balanced equations.
- Describe the uses of sulfur and its compounds in industry, agriculture, and medicine.
- Explain the trend in oxidizing power of halogens down group 17. Support your answer with reactions and ionic equations.
- Describe the reactions of halogens with hydrogen. Compare their reactivity trend and write balanced chemical equations.
- Describe how chlorine purifies drinking water. Include chemical reactions and the role of HClO and ClO⁻.
- Describe the displacement reactions of halogens with halide ions and relate them to oxidizing strength.







